Additive-controlled regiodivergent catalytic alkyne hydrosilylation reactions. Chinese Chemical Society. Journal CCS Chemistry DOI 10.31635/ccschem.025.202405338 ...

A combination of organoboron and radical chemistry generates unusual trans-selectivity in hydroboration of alkynes. The use of N-heterocyclic carbene boranes is key to the success of this chemical ...

The alkene or alkyne products are widely used, for example, in poly­merizations to make plastics. Chemists have been interested in extending metathesis methods to carbon’s heavier analogs, ...