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The Grignard Reagents market is witnessing steady demand across pharmaceuticals, agrochemicals, and chemical synthesis due to their versatility in or ...
Petten, C.F., Kalviri, H.A. and Kerton, F.M. (2015) Halodehydroxylation of Alcohols to Yield Benzylic and Alkyl Halides in Ionic Liquids. Sustainable Chemical Processes, 3, Article No. 16.
Chemistry students are usually taught that alkyl groups are electron-donating and hence that tertiary carbocations are more stable than primary carbocations. This understanding is often used to ...
α-FAPbI3, a promising solar cell material with a cubic perovskite structure that is metastable at room temperature, can be stabilized by introducing a pseudo-halide ion like thiocyanate (SCN–) into ...
Indeed, a long time ago, Nosek 12 described the dimerization of benzyl and n-alkyl halides promoted by zinc/silver in water under reflux with yields up to 70%. Chan 9 obtained a similar coupling ...
Draft Screening Assessment for Alkyl Halides Group (published on March 5, 2022 for a 60-day public comment period ending on May 4, 2022) Risk Management Scope for the Alkyl Halides Group, specifically ...
The traditional three-dimensional (3D) halide perovskites (HPs) have experienced rapid development due to their highly power conversion efficiency (PCE). However, the instability of 3D perovskite on ...
Subsequently, we developed multicomponent carbonylation reactions of alkyl halides using NHC-Cu catalysts (NHC = N-heterocyclic carbene). These reactions operate by radical mechanisms, converting ...
In case of primary alkyl halides carbocation is highly unstable and steric hinderance is very less. So, primary alkyl halide would prefer to undergo S N 2reaction.
Inspired by Baran’s proposal that alkyl radical could add to nitrosoarene, formed by the reduction of nitroarene 14, we envisioned that reductive coupling of nitroarenes and alkyl halides might ...
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